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Beilstein J. Org. Chem. 2014, 10, 2912–2919, doi:10.3762/bjoc.10.309
Graphical Abstract
Figure 1: 2,2':5',2"-Terthiophene.
Scheme 1: Palladium-catalyzed direct arylation using 2,5-dibromothiophene and 2-ethyl-4-methylthiazole as cou...
Scheme 2: Reactivity of 2,5-dibromothiophene with different heteroarenes.
Scheme 3: Reactivity of 2,5-dibromo-3-methylthiophene with different heteroarenes.
Scheme 4: Sequential diheteroarylation of 2,5-dibromothiophene.
Scheme 5: Sequential diheteroarylation of 2,5-dibromothiophene.
Scheme 6: Heteroarylation of 2-bromothiophene.
Scheme 7: Reactivity of 4,7-dibromobenzothiadiazole.